151Eu Mössbauer spectroscopy and x-ray-diffraction studies on the Pb2Ba2EuCu3O8+[delta] system
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© 1994 American Physical Society (APS). This is the accepted version of the following article: Lindén, J. & Lippmaa, M. & Miettinen, J. & Tittonen, I. & Katila, T. & Karppinen, Maarit & Niinistö, L. 1994. 151Eu Mössbauer spectroscopy and x-ray-diffraction studies on the Pb2Ba2EuCu3O8+[delta] system. Physical Review B. Volume 50, Issue 21. 16040-16043. ISSN 1550-235X (electronic). DOI: 10.1103/physrevb.50.16040, which has been published in final form at http://journals.aps.org/prb/abstract/10.1103/PhysRevB.50.16040.
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School of Chemical Technology |
A1 Alkuperäisartikkeli tieteellisessä aikakauslehdessä
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Date
1994
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Language
en
Pages
16040-16043
Series
Physical Review B, Volume 50, Issue 21
Abstract
Simultaneous replacement of Sr by Ba and Y by Eu in the Pb-2213 system was found to yield single-phase Pb2Ba2EuCu3O8+δ samples, suitable for Eu151 Mössbauer measurements. The samples were synthesized by a solid-state reaction of metal oxides and carbonates under an inert atmosphere. An oxygen-rich sample corresponding to δ=1.79 was obtained by annealing the as-synthesized material (δ=0.16) in oxygen. The oxygen annealing increased the size of the lattice constants and led to an orthorhombic-to-tetragonal phase transition of the structure. The samples were also oriented in an 11.7-T magnetic field. The x-ray-diffraction spectra showed that the c axes tended to orient perpendicular to the applied field. The measured Mössbauer spectra exhibited an electric quadrupole interaction typical of the Eu site in high-Tc cuprates. The average orientation angles obtained from fittings of the Mössbauer spectra were in accordance with the results from the x-ray-diffraction measurements.Description
Keywords
Mössbauer spectroscopy, XRD
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Citation
Lindén, J. & Lippmaa, M. & Miettinen, J. & Tittonen, I. & Katila, T. & Karppinen, Maarit & Niinistö, L. 1994. 151Eu Mössbauer spectroscopy and x-ray-diffraction studies on the Pb2Ba2EuCu3O8+[delta] system. Physical Review B. Volume 50, Issue 21. 16040-16043. ISSN 1550-235X (electronic). DOI: 10.1103/physrevb.50.16040.