Carbocatalytic Oxidative Dehydrogenative Couplings of (Hetero)Aryls by Oxidized Multi-Walled Carbon Nanotubes in Liquid Phase
dc.contributor | Aalto-yliopisto | fi |
dc.contributor | Aalto University | en |
dc.contributor.author | Wirtanen, Tom | en_US |
dc.contributor.author | Aikonen, Santeri | en_US |
dc.contributor.author | Muuronen, Mikko | en_US |
dc.contributor.author | Melchionna, Michele | en_US |
dc.contributor.author | Kemell, Marianna | en_US |
dc.contributor.author | Davodi, Fatemeh | en_US |
dc.contributor.author | Kallio, Tanja | en_US |
dc.contributor.author | Hu, Tao | en_US |
dc.contributor.author | Helaja, Juho | en_US |
dc.contributor.department | Department of Chemistry and Materials Science | en |
dc.contributor.groupauthor | Electrochemical Energy Conversion | en |
dc.contributor.organization | University of Helsinki | en_US |
dc.contributor.organization | Università degli studi di Trieste | en_US |
dc.contributor.organization | University of Oulu | en_US |
dc.date.accessioned | 2020-01-02T14:05:17Z | |
dc.date.available | 2020-01-02T14:05:17Z | |
dc.date.embargo | info:eu-repo/date/embargoEnd/2020-01-02 | en_US |
dc.date.issued | 2019-01-01 | en_US |
dc.description.abstract | HNO3-oxidized carbon nanotubes catalyze oxidative dehydrogenative (ODH) carbon–carbon bond formation between electron-rich (hetero)aryls with O2 as a terminal oxidant. The recyclable carbocatalytic method provides a convenient and an operationally easy synthetic protocol for accessing various benzofused homodimers, biaryls, triphenylenes, and related benzofused heteroaryls that are highly useful frameworks for material chemistry applications. Carbonyls/quinones are the catalytically active site of the carbocatalyst as indicated by model compounds and titration experiments. Further investigations of the reaction mechanism with a combination of experimental and DFT methods support the competing nature of acid-catalyzed and radical cationic ODHs, and indicate that both mechanisms operate with the current material. | en |
dc.description.version | Peer reviewed | en |
dc.format.mimetype | application/pdf | en_US |
dc.identifier.citation | Wirtanen, T, Aikonen, S, Muuronen, M, Melchionna, M, Kemell, M, Davodi, F, Kallio, T, Hu, T & Helaja, J 2019, ' Carbocatalytic Oxidative Dehydrogenative Couplings of (Hetero)Aryls by Oxidized Multi-Walled Carbon Nanotubes in Liquid Phase ', Chemistry: A European Journal . https://doi.org/10.1002/chem.201903054 | en |
dc.identifier.doi | 10.1002/chem.201903054 | en_US |
dc.identifier.issn | 0947-6539 | |
dc.identifier.issn | 1521-3765 | |
dc.identifier.other | PURE UUID: 9dac82a2-8b17-4809-bc89-d6f4391abb81 | en_US |
dc.identifier.other | PURE ITEMURL: https://research.aalto.fi/en/publications/9dac82a2-8b17-4809-bc89-d6f4391abb81 | en_US |
dc.identifier.other | PURE LINK: http://www.scopus.com/inward/record.url?scp=85071622997&partnerID=8YFLogxK | en_US |
dc.identifier.other | PURE FILEURL: https://research.aalto.fi/files/39211254/CHEM_Wirtanen_et_al_Carbocatalytic_Oxidative_2019_EurJourChem.pdf | en_US |
dc.identifier.uri | https://aaltodoc.aalto.fi/handle/123456789/42149 | |
dc.identifier.urn | URN:NBN:fi:aalto-202001021260 | |
dc.language.iso | en | en |
dc.publisher | WILEY-V C H VERLAG GMBH | |
dc.relation.ispartofseries | Chemistry - A European Journal | en |
dc.rights | openAccess | en |
dc.subject.keyword | carbon nanotubes | en_US |
dc.subject.keyword | C−C coupling | en_US |
dc.subject.keyword | heterogeneous catalysis | en_US |
dc.subject.keyword | oxidative dehydrogenative coupling | en_US |
dc.title | Carbocatalytic Oxidative Dehydrogenative Couplings of (Hetero)Aryls by Oxidized Multi-Walled Carbon Nanotubes in Liquid Phase | en |
dc.type | A1 Alkuperäisartikkeli tieteellisessä aikakauslehdessä | fi |
dc.type.version | acceptedVersion |