Hydrogenation of 4-deoxy-beta-L-threo-hex-4-enopyranosyluronic acid sodium salt attached to xylodiose or xylotriose

dc.contributorAalto-yliopistofi
dc.contributorAalto Universityen
dc.contributor.authorSelkälä, Sami A.
dc.contributor.authorAlakurtti, Sami
dc.contributor.authorKoskinen, Ari M.P.
dc.contributor.departmentDepartment of Chemistryen
dc.date.accessioned2016-09-23T09:21:00Z
dc.date.issued2001
dc.description.abstractA sodium salt of 4-deoxy-b-L-threo -hex-4-enopyranosyluronic acid 1 attached to xylodiose or xylotriose is hydro-genated for the first time. Moreover, the double bond of 4-deoxy-b-L-threo -hex-4-enopyranosyluronic acid sodium salt 1 can be reduced by hydrogenation in water without removing the allylic hydroxyl group. Highly active homogeneous catalysts and heterogeneous catalysts were tested and only palladium or platinum on charcoal catalysts were found to be active in this case.en
dc.description.versionPeer revieweden
dc.format.extent3215-3217
dc.format.mimetypeapplication/pdf
dc.identifier.citationSelkälä , S A , Alakurtti , S & Koskinen , A M P 2001 , ' Hydrogenation of 4-deoxy-beta-L-threo-hex-4-enopyranosyluronic acid sodium salt attached to xylodiose or xylotriose ' , Tetrahedron Letters , vol. 42 , pp. 3215-3217 . https://doi.org/10.1016/S0040-4039(01)00398-7en
dc.identifier.doi10.1016/S0040-4039(01)00398-7
dc.identifier.issn1873-3581
dc.identifier.otherPURE UUID: 1fe3f6e9-a313-4c44-a18d-b809ab68c3cf
dc.identifier.otherPURE ITEMURL: https://research.aalto.fi/en/publications/1fe3f6e9-a313-4c44-a18d-b809ab68c3cf
dc.identifier.otherPURE FILEURL: https://research.aalto.fi/files/7159101/Hydrogenation_of_4_deoxy_b_L_threo_hex_4_enopyrano.pdf
dc.identifier.urihttps://aaltodoc.aalto.fi/handle/123456789/22401
dc.identifier.urnURN:NBN:fi:aalto-201609234404
dc.language.isoenen
dc.relation.ispartofseriesTetrahedron Lettersen
dc.relation.ispartofseriesVolume 42en
dc.rightsopenAccessen
dc.subject.keywordheterogenous catalysis
dc.subject.keywordhomogenous catalysis
dc.subject.keywordhydrogenation
dc.subject.keywordunsaturated acid
dc.titleHydrogenation of 4-deoxy-beta-L-threo-hex-4-enopyranosyluronic acid sodium salt attached to xylodiose or xylotrioseen
dc.typeA1 Alkuperäisartikkeli tieteellisessä aikakauslehdessäfi
dc.type.versionacceptedVersion
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