Hierarchical Layer Engineering Using Supramolecular Double-Comb Diblock Copolymers

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openAccess

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Journal Title

Journal ISSN

Volume Title

A1 Alkuperäisartikkeli tieteellisessä aikakauslehdessä

Date

2016

Major/Subject

Mcode

Degree programme

Language

en

Pages

13081-13085

Series

ANGEWANDTE CHEMIE, Volume 55, issue 42

Abstract

The formation of unusual multilayered parallel lamellae-in-lamellae in symmetric supramolecular double-comb diblock copolymers is presented. While keeping the concentration of surfactant fixed, the number of internal layers was found to increase with molecular weight M up to 34 for the largest block copolymer. The number of internal structures n was established to scale as M0.67 and therefore enables easy design of such structures with great precision.

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Keywords

Block copolymers, Morphology, Supramolecular self-assembly

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Citation

Hofman, A H, Reza, M, Ruokolainen, J, tenBrinke, G & Loos, K 2016, ' Hierarchical Layer Engineering Using Supramolecular Double-Comb Diblock Copolymers ', Angewandte Chemie, vol. 55, no. 42, pp. 13081-13085 . https://doi.org/10.1002/anie.201606890