Hierarchical Layer Engineering Using Supramolecular Double-Comb Diblock Copolymers

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Journal Title
Journal ISSN
Volume Title
A1 Alkuperäisartikkeli tieteellisessä aikakauslehdessä
Date
2016
Major/Subject
Mcode
Degree programme
Language
en
Pages
13081-13085
Series
ANGEWANDTE CHEMIE, Volume 55, issue 42
Abstract
The formation of unusual multilayered parallel lamellae-in-lamellae in symmetric supramolecular double-comb diblock copolymers is presented. While keeping the concentration of surfactant fixed, the number of internal layers was found to increase with molecular weight M up to 34 for the largest block copolymer. The number of internal structures n was established to scale as M0.67 and therefore enables easy design of such structures with great precision.
Description
Keywords
Block copolymers, Morphology, Supramolecular self-assembly
Other note
Citation
Hofman , A H , Reza , M , Ruokolainen , J , tenBrinke , G & Loos , K 2016 , ' Hierarchical Layer Engineering Using Supramolecular Double-Comb Diblock Copolymers ' , Angewandte Chemie , vol. 55 , no. 42 , pp. 13081-13085 . https://doi.org/10.1002/anie.201606890