A Neutron Diffraction and Quantum-Chemical Study of [Mn(ND3)6](N3)2
No Thumbnail Available
Access rights
openAccess
acceptedVersion
URL
Journal Title
Journal ISSN
Volume Title
A1 Alkuperäisartikkeli tieteellisessä aikakauslehdessä
This publication is imported from Aalto University research portal.
View publication in the Research portal (opens in new window)
View/Open full text file from the Research portal (opens in new window)
Other link related to publication (opens in new window)
View publication in the Research portal (opens in new window)
View/Open full text file from the Research portal (opens in new window)
Other link related to publication (opens in new window)
Date
2018-06-11
Major/Subject
Mcode
Degree programme
Language
en
Pages
Series
Zeitschrift fur Anorganische und Allgemeine Chemie, Volume 644, issue 21, pp. 1349-1353
Abstract
[Mn(ND3)6](N3)2 was obtained by careful decomposition of [Mn(ND3)6](N3)2·4ND3 at room temperature. It crystallizes in the monoclinic space group I2/m with a = 8.5905(5), b = 6.8506(4), c = 9.7530(6) Å, β = 94.618(6)°, V = 572.10(6) Å3, Z = 2, at T = 3 K. Its crystal structure was elucidated using powder neutron diffraction and confirmed by quantum chemical calculations. The MnII cation is coordinated octrahedron-like by ND3 ligands. The azide anion is linear with 178.7(10)° and shows N-N distances of 1.178(11) and 1.180(12) Å.Description
Keywords
Azides, Crystal structure, Liquid ammonia, Manganese, Neutron diffraction
Other note
Citation
Ivlev, S I, Müller, T G, Karttunen, A J, Hoelzel, M & Kraus, F 2018, ' A Neutron Diffraction and Quantum-Chemical Study of [Mn(ND 3 ) 6 ](N 3 ) 2 ', Zeitschrift fur Anorganische und Allgemeine Chemie, vol. 644, no. 21, pp. 1349-1353 . https://doi.org/10.1002/zaac.201800217