Furfural Hydrotreatment Applying Isopropanol as a Solvent

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dc.contributor Aalto-yliopisto fi
dc.contributor Aalto University en
dc.contributor.author Jaatinen, Salla
dc.contributor.author Karinen, Reetta
dc.date.accessioned 2019-05-06T09:16:33Z
dc.date.available 2019-05-06T09:16:33Z
dc.date.issued 2017-11-01
dc.identifier.citation Jaatinen , S & Karinen , R 2017 , ' Furfural Hydrotreatment Applying Isopropanol as a Solvent : The Case of Acetone Formation ' Topics in Catalysis , vol. 60 , no. 17-18 , pp. 1473-1481 . https://doi.org/10.1007/s11244-017-0828-7 en
dc.identifier.issn 1022-5528
dc.identifier.issn 1572-9028
dc.identifier.other PURE UUID: 84614ea3-2da8-4b13-b9a4-3a83fd753122
dc.identifier.other PURE ITEMURL: https://research.aalto.fi/en/publications/furfural-hydrotreatment-applying-isopropanol-as-a-solvent(84614ea3-2da8-4b13-b9a4-3a83fd753122).html
dc.identifier.other PURE LINK: http://www.scopus.com/inward/record.url?scp=85020135239&partnerID=8YFLogxK
dc.identifier.other PURE FILEURL: https://research.aalto.fi/files/33354786/CHEM_Jaatinen_et_al_Furfural_Hydrotreatment_2017_Topics_in_Catalysis.pdf
dc.identifier.uri https://aaltodoc.aalto.fi/handle/123456789/37709
dc.description.abstract In this study, acetone formation was investigated as a side reaction in furfural hydrotreatment applying isopropanol as a solvent. Acetone formation was observed to depend strongly on the metal and metal loading of catalysts as copper, nickel, and iron catalysts supported on activated carbon were studied. Furfural has an important role in acetone formation: the initial formation rate for acetone was high as long as furfural reacted further. After furfural was consumed the acetone formation decelerated except with the catalysts including iron. Two formation mechanisms were derived: first mechanism includes direct and transfer hydrogenation of furfural and isopropanol dehydrogenation, as mechanism two consists only of isopropanol dehydrogenation. Another novel discovery of the study was the confirmation of the formation mechanism for 2-methylfuran through transfer hydrogenation of furfuryl alcohol in the experiments. In conclusion, the acetone formation as a side product was observed significant and could not be totally prevented. en
dc.format.extent 9
dc.format.extent 1473-1481
dc.format.mimetype application/pdf
dc.language.iso en en
dc.publisher SPRINGER/PLENUM PUBLISHERS
dc.relation.ispartofseries Topics in Catalysis en
dc.relation.ispartofseries Volume 60, issue 17-18 en
dc.rights openAccess en
dc.subject.other Catalysis en
dc.subject.other Chemistry(all) en
dc.subject.other 215 Chemical engineering en
dc.title Furfural Hydrotreatment Applying Isopropanol as a Solvent en
dc.type A1 Alkuperäisartikkeli tieteellisessä aikakauslehdessä fi
dc.description.version Peer reviewed en
dc.contributor.department Department of Chemical and Metallurgical Engineering
dc.contributor.department Department of Chemical and Metallurgical Engineering en
dc.subject.keyword Acetone
dc.subject.keyword Catalyst
dc.subject.keyword Furfural
dc.subject.keyword Hydrotreatment
dc.subject.keyword Isopropanol
dc.subject.keyword Catalysis
dc.subject.keyword Chemistry(all)
dc.subject.keyword 215 Chemical engineering
dc.identifier.urn URN:NBN:fi:aalto-201905062828
dc.identifier.doi 10.1007/s11244-017-0828-7
dc.type.version acceptedVersion
dc.date.embargo info:eu-repo/date/embargoEnd/2018-11-02


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