A 1D Coordination Polymer of UF5 with HCN as a Ligand

Scheibe, Benjamin; Rudel, Stefan S.; Buchner, Magnus R.; Karttunen, Antti J.; Kraus, Florian

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A 1D Coordination Polymer of UF5 with HCN as a Ligand

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Title:	A 1D Coordination Polymer of UF5 with HCN as a Ligand
Author(s):	Scheibe, Benjamin ; Rudel, Stefan S. ; Buchner, Magnus R. ; Karttunen, Antti J. ; Kraus, Florian
Date:	2017-01-05
Language:	en
Pages:	5 291-295
Department:	University of Marburg Department of Chemistry Department of Chemistry and Materials Science
Series:	CHEMISTRY: A EUROPEAN JOURNAL, Volume 23, issue 2
ISSN:	0947-6539 1521-3765
DOI-number:	10.1002/chem.201605293
Subject:	Chemistry(all), 116 Chemical sciences
Keywords:	coordination polymer, cyanides, fluorides, uranium, X-ray diffraction, Chemistry(all), 116 Chemical sciences
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Citation: Scheibe , B , Rudel , S S , Buchner , M R , Karttunen , A J & Kraus , F 2017 , ' A 1D Coordination Polymer of UF 5 with HCN as a Ligand ' CHEMISTRY: A EUROPEAN JOURNAL , vol 23 , no. 2 , pp. 291-295 . DOI: 10.1002/chem.201605293
Abstract: β-Uranium(V) fluoride was reacted with liquid anhydrous hydrogen cyanide to obtain a 1D coordination polymer with the composition (Formula presented.) [UF5(HCN)2], (Formula presented.) [UF4/1F2/2- (HCN)2/1], revealed by single-crystal X-ray structure determination. The reaction system was furthermore studied by means of vibrational and NMR spectroscopy, as well as by quantum chemical calculations. The compound presents the first described polymeric HCN Lewis adduct and the first HCN adduct of a uranium fluoride.

Permanent link to this item: http://urn.fi/URN:NBN:fi:aalto-201811095622 Email this Export to RefWorks QR Code Print BibTex Tweet