A 1D Coordination Polymer of UF5 with HCN as a Ligand

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A 1D Coordination Polymer of UF5 with HCN as a Ligand

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Title: A 1D Coordination Polymer of UF5 with HCN as a Ligand
Author(s): Scheibe, Benjamin ; Rudel, Stefan S. ; Buchner, Magnus R. ; Karttunen, Antti J. ; Kraus, Florian
Date: 2017-01-05
Language: en
Pages: 5
291-295
Department: University of Marburg
Department of Chemistry
Department of Chemistry and Materials Science
Series: CHEMISTRY: A EUROPEAN JOURNAL, Volume 23, issue 2
ISSN: 0947-6539
1521-3765
DOI-number: 10.1002/chem.201605293
Subject: Chemistry(all), 116 Chemical sciences
Keywords: coordination polymer, cyanides, fluorides, uranium, X-ray diffraction, Chemistry(all), 116 Chemical sciences
 

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Citation:

Scheibe , B , Rudel , S S , Buchner , M R , Karttunen , A J & Kraus , F 2017 , ' A 1D Coordination Polymer of UF 5 with HCN as a Ligand ' , CHEMISTRY: A EUROPEAN JOURNAL , vol. 23 , no. 2 , pp. 291-295 . https://doi.org/10.1002/chem.201605293

Abstract:

β-Uranium(V) fluoride was reacted with liquid anhydrous hydrogen cyanide to obtain a 1D coordination polymer with the composition (Formula presented.) [UF5(HCN)2], (Formula presented.) [UF4/1F2/2- (HCN)2/1], revealed by single-crystal X-ray structure determination. The reaction system was furthermore studied by means of vibrational and NMR spectroscopy, as well as by quantum chemical calculations. The compound presents the first described polymeric HCN Lewis adduct and the first HCN adduct of a uranium fluoride.
 
Permanent link to this item:  http://urn.fi/URN:NBN:fi:aalto-201811095622
 
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