Activity of Supercooled Water on the Ice Curve and Other Thermodynamic Properties of Liquid Water up to the Boiling Point at Standard Pressure

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dc.contributor Aalto-yliopisto fi
dc.contributor Aalto University en
dc.contributor.author Sippola, Hannu
dc.contributor.author Taskinen, Pekka
dc.date.accessioned 2018-09-04T11:14:32Z
dc.date.available 2018-09-04T11:14:32Z
dc.date.issued 2018-08-09
dc.identifier.citation Sippola , H & Taskinen , P 2018 , ' Activity of Supercooled Water on the Ice Curve and Other Thermodynamic Properties of Liquid Water up to the Boiling Point at Standard Pressure ' Journal of Chemical and Engineering Data , vol 63 , no. 8 , pp. 2986-2998 . DOI: 10.1021/acs.jced.8b00251 en
dc.identifier.issn 0021-9568
dc.identifier.issn 1520-5134
dc.identifier.other PURE UUID: eb81649f-d56d-4ec2-b495-8dfe747c9e17
dc.identifier.other PURE ITEMURL: https://research.aalto.fi/en/publications/activity-of-supercooled-water-on-the-ice-curve-and-other-thermodynamic-properties-of-liquid-water-up-to-the-boiling-point-at-standard-pressure(eb81649f-d56d-4ec2-b495-8dfe747c9e17).html
dc.identifier.other PURE LINK: http://www.scopus.com/inward/record.url?scp=85051438679&partnerID=8YFLogxK
dc.identifier.other PURE FILEURL: https://research.aalto.fi/files/27526870/CHEM_Sippola_activity_of_acs.jced.8b00251.pdf
dc.identifier.uri https://aaltodoc.aalto.fi/handle/123456789/33829
dc.description.abstract A simple model for thermodynamic properties of water from subzero temperatures up to 373 K was derived at ambient pressure. The heat capacity of supercooled water was assessed as lambda transition. The obtained properties for supercooled water such as heat capacity, vapor pressure, density and thermal expansion are in excellent agreement with literature data. Activity of water on ice curve, independent of used electrolyte and Debye-Hückel constant applied in modeling, is also calculated. Thus, the ice curve activity of supercooled water can be used as a universal basis for thermodynamic modeling of aqueous solutions, precipitating hydrated and anhydrous solids. A simple model for heat capacity, density and thermal expansion of ice are also derived from 170 K up to melting point. en
dc.format.extent 13
dc.format.extent 2986-2998
dc.format.mimetype application/pdf
dc.language.iso en en
dc.relation.ispartofseries Journal of Chemical and Engineering Data en
dc.relation.ispartofseries Volume 63, issue 8 en
dc.rights openAccess en
dc.subject.other Chemistry(all) en
dc.subject.other Chemical Engineering(all) en
dc.subject.other 116 Chemical sciences en
dc.title Activity of Supercooled Water on the Ice Curve and Other Thermodynamic Properties of Liquid Water up to the Boiling Point at Standard Pressure en
dc.type A1 Alkuperäisartikkeli tieteellisessä aikakauslehdessä fi
dc.description.version Peer reviewed en
dc.contributor.department Mineral Processing and Recycling
dc.contributor.department Department of Chemical and Metallurgical Engineering
dc.subject.keyword Chemistry(all)
dc.subject.keyword Chemical Engineering(all)
dc.subject.keyword 116 Chemical sciences
dc.identifier.urn URN:NBN:fi:aalto-201809044949
dc.identifier.doi 10.1021/acs.jced.8b00251
dc.type.version publishedVersion


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