The oxidation of bitumen witnessed in-situ by infrared spectroscopy

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dc.contributor Aalto-yliopisto fi
dc.contributor Aalto University en
dc.contributor.author Makowska, Michalina
dc.contributor.author Hartikainen, Ari
dc.contributor.author Pellinen, Terhi
dc.date.accessioned 2018-05-22T14:39:41Z
dc.date.available 2018-05-22T14:39:41Z
dc.date.issued 2017-06-01
dc.identifier.citation Makowska , M , Hartikainen , A & Pellinen , T 2017 , ' The oxidation of bitumen witnessed in-situ by infrared spectroscopy ' MATERIALS AND STRUCTURES , vol 50 , no. 3 , 189 . DOI: 10.1617/s11527-017-1058-y en
dc.identifier.issn 1359-5997
dc.identifier.issn 1871-6873
dc.identifier.other PURE UUID: 72e9fce0-726b-4961-84d0-426c427155c7
dc.identifier.other PURE ITEMURL: https://research.aalto.fi/en/publications/the-oxidation-of-bitumen-witnessed-insitu-by-infrared-spectroscopy(72e9fce0-726b-4961-84d0-426c427155c7).html
dc.identifier.other PURE LINK: http://www.scopus.com/inward/record.url?scp=85020543840&partnerID=8YFLogxK
dc.identifier.other PURE FILEURL: https://research.aalto.fi/files/20505618/10.1617_s11527_017_1058_y.pdf
dc.identifier.uri https://aaltodoc.aalto.fi/handle/123456789/30984
dc.description.abstract During the production and recycling of asphalt concrete, bitumen in contact with inorganic particles is exposed to air at high temperatures. As a result an oxidation of bitumen, also known as aging, occurs. The reaction between bitumen and air at 163 °C was studied insitu with and without the presence of inorganic impurities by means of fourier transform infrared spectroscopy in the attenuated reflectance mode. This oxidation was discovered to be a step-wise reaction facilitated by the oxidation of thiols and creation of peroxides within the system. The rate of reaction was demonstrated to depend on the type of impurity present, of which iron (III) chloride was the strongest catalyst. It was further demonstrated that the oxidation reaction is inhibited by the adsorption of thiol species present in the system on copper particles. Combining copper with the iron (III) chloride-containing system also resulted in the inhibition of signal increase in the sulfoxide region of the spectra. The results of this preliminary research on the bitumen oxidation reaction presented are proposed for further research regarding control of aging of asphalt concrete, especially during the recycling works. en
dc.format.extent 17
dc.format.mimetype application/pdf
dc.language.iso en en
dc.relation.ispartofseries MATERIALS AND STRUCTURES en
dc.relation.ispartofseries Volume 50, issue 3 en
dc.rights openAccess en
dc.subject.other Civil and Structural Engineering en
dc.subject.other Building and Construction en
dc.subject.other Materials Science(all) en
dc.subject.other Mechanics of Materials en
dc.subject.other 212 Civil and construction engineering en
dc.subject.other recycling en
dc.title The oxidation of bitumen witnessed in-situ by infrared spectroscopy en
dc.type A1 Alkuperäisartikkeli tieteellisessä aikakauslehdessä fi
dc.description.version Peer reviewed en
dc.contributor.department Department of Civil Engineering
dc.subject.keyword Asphalt
dc.subject.keyword ATR
dc.subject.keyword Bitumen
dc.subject.keyword FT-IR
dc.subject.keyword Oxidation
dc.subject.keyword Recycling
dc.subject.keyword Civil and Structural Engineering
dc.subject.keyword Building and Construction
dc.subject.keyword Materials Science(all)
dc.subject.keyword Mechanics of Materials
dc.subject.keyword 212 Civil and construction engineering
dc.subject.keyword recycling
dc.identifier.urn URN:NBN:fi:aalto-201805222424
dc.identifier.doi 10.1617/s11527-017-1058-y
dc.type.version publishedVersion


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