Nanocomposite films based on cellulose nanofibrils and water-soluble polysaccharides

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dc.contributor Aalto-yliopisto fi
dc.contributor Aalto University en
dc.contributor.author Lucenius, Jessica
dc.contributor.author Parikka, Kirsti
dc.contributor.author Österberg, Monika
dc.date.accessioned 2016-11-08T12:10:25Z
dc.date.issued 2014-12
dc.identifier.citation Lucenius , J , Parikka , K & Österberg , M 2014 , ' Nanocomposite films based on cellulose nanofibrils and water-soluble polysaccharides ' REACTIVE AND FUNCTIONAL POLYMERS , vol 85 , pp. 167-174 . DOI: 10.1016/j.reactfunctpolym.2014.08.001 en
dc.identifier.issn 1381-5148
dc.identifier.issn 1873-166X
dc.identifier.other PURE UUID: 3e455e37-4ac6-44b1-9984-17e9398683d1
dc.identifier.other PURE ITEMURL: https://research.aalto.fi/en/publications/nanocomposite-films-based-on-cellulose-nanofibrils-and-watersoluble-polysaccharides(3e455e37-4ac6-44b1-9984-17e9398683d1).html
dc.identifier.other PURE LINK: http://www.scopus.com/inward/record.url?scp=84912534007&partnerID=8YFLogxK
dc.identifier.other PURE FILEURL: https://research.aalto.fi/files/9070788/Lucenius_revised_Manuscript.pdf
dc.identifier.uri https://aaltodoc.aalto.fi/handle/123456789/23433
dc.description.abstract All-polysaccharide composite films were prepared from native, unmodified cellulose nanofibrils (CNF) mixed with various natural water-soluble polysaccharides like carboxymethyl cellulose, galactoglucomannan, xyloglucan and guar gum. Composite films were manufactured by pressurized filtration and hot pressing. The mechanical properties of the films were systematically evaluated in the dry and the wet state. GG was furthermore selectively oxidized using galactose oxidase (EC 1.1.3.9), and the effect of the degree of oxidation on the final composite film properties was shown. It was found that all the tested polysaccharides increased the strength and toughness of the dry composite films at 2 weight percent (wt.%) addition to CNF. After soaking the samples for 24 h in water, striking differences between the samples were found: already at 2 wt.% CMC the wet strength of the composite films diminished, while the uncharged polysaccharides improved the wet strength. For example, the addition of 2 wt.% GGM increased Young's modulus by a factor of 1.3, the tensile strength by a factor of 2.8, and the toughness by a factor of 3.4. The results are discussed in relation to the amount of water absorbed in the films and possible reasons for the improved properties are suggested. en
dc.format.extent 8
dc.format.extent 167-174
dc.format.mimetype application/pdf
dc.language.iso en en
dc.relation.ispartofseries REACTIVE AND FUNCTIONAL POLYMERS en
dc.relation.ispartofseries Volume 85 en
dc.rights openAccess en
dc.subject.other Materials Chemistry en
dc.subject.other Polymers and Plastics en
dc.subject.other Chemistry(all) en
dc.subject.other Chemical Engineering(all) en
dc.subject.other Environmental Chemistry en
dc.subject.other Biochemistry en
dc.subject.other 216 Materials engineering en
dc.title Nanocomposite films based on cellulose nanofibrils and water-soluble polysaccharides en
dc.type A1 Alkuperäisartikkeli tieteellisessä aikakauslehdessä fi
dc.description.version Peer reviewed en
dc.contributor.department Department of Forest Products Technology
dc.subject.keyword Cellulose nanofibrils
dc.subject.keyword Composite film
dc.subject.keyword Galactoglucomannan
dc.subject.keyword Guar gum
dc.subject.keyword Tensile strength
dc.subject.keyword Materials Chemistry
dc.subject.keyword Polymers and Plastics
dc.subject.keyword Chemistry(all)
dc.subject.keyword Chemical Engineering(all)
dc.subject.keyword Environmental Chemistry
dc.subject.keyword Biochemistry
dc.subject.keyword 216 Materials engineering
dc.identifier.urn URN:NBN:fi:aalto-201611085521
dc.identifier.doi 10.1016/j.reactfunctpolym.2014.08.001
dc.type.version acceptedVersion


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