2-Thioanyldichlorophosphine, new starting material for the preparation of multidentate phosphine ligands: syntheses and characterisation of derivatives of 2-anisyl- and 2-thioanisyldichlorophosphines

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dc.contributor Aalto-yliopisto fi
dc.contributor Aalto University en
dc.contributor.author Laitinen, R.H
dc.contributor.author Heikkinen, V.
dc.contributor.author Haukka, M.
dc.contributor.author Koskinen, A.M.P.
dc.contributor.author Pursiainen, J.
dc.date.accessioned 2016-09-23T09:21:17Z
dc.date.issued 2000
dc.identifier.citation Laitinen , R H , Heikkinen , V , Haukka , M , Koskinen , A M P & Pursiainen , J 2000 , ' 2-Thioanyldichlorophosphine, new starting material for the preparation of multidentate phosphine ligands: syntheses and characterisation of derivatives of 2-anisyl- and 2-thioanisyldichlorophosphines ' J. Organomet. Chem. , no. 598 , pp. 235-242 . DOI: http://dx.doi.org/10.1016/S0022-328X(99)00711-1 en
dc.identifier.other PURE UUID: 291c3f41-a49e-4a58-ac00-55f9f37b898a
dc.identifier.other PURE ITEMURL: https://research.aalto.fi/en/publications/2thioanyldichlorophosphine-new-starting-material-for-the-preparation-of-multidentate-phosphine-ligands-syntheses-and-characterisation-of-derivatives-of-2anisyl-and-2thioanisyldichlorophosphines(291c3f41-a49e-4a58-ac00-55f9f37b898a).html
dc.identifier.other PURE FILEURL: https://research.aalto.fi/files/7157213/2_Thioanisyldichlorophosphine_new_starting_materia.pdf
dc.identifier.uri https://aaltodoc.aalto.fi/handle/123456789/22405
dc.description.abstract A new aryldichlorophosphine, 2-thioanisyldichlorophosphine, and its anisyl analogue, 2-anisyldichlorophosphine, were prepared by using an organozinc halide reagent of 2-thioanisole or 2-anisole with ethereal solution of PCl3 in refluxing conditions. From these aryldichlorophosphines, eight new multidentate phosphine ligands containing 2-thioanisyl, 4-thioanisyl, 2-anisyl, 1-naphthyl and 9-anthracenyl groups were synthesized and characterized. Characterization was based mainly on NMR spectroscopy and X-ray crystallography. The crystal structures of six ligands are reported. The electronic effects on basicity of ligands are discussed. en
dc.format.extent 235-242
dc.format.mimetype application/pdf
dc.language.iso en en
dc.relation.ispartofseries J. Organomet. Chem. en
dc.relation.ispartofseries issue 598 en
dc.rights openAccess en
dc.subject.other 116 Chemical sciences en
dc.title 2-Thioanyldichlorophosphine, new starting material for the preparation of multidentate phosphine ligands: syntheses and characterisation of derivatives of 2-anisyl- and 2-thioanisyldichlorophosphines en
dc.type A1 Alkuperäisartikkeli tieteellisessä aikakauslehdessä fi
dc.description.version Peer reviewed en
dc.contributor.department Department of Chemistry en
dc.subject.keyword ligands
dc.subject.keyword phosphine
dc.subject.keyword synthesis
dc.subject.keyword thioanyldichlorophosphine
dc.subject.keyword 116 Chemical sciences
dc.identifier.urn URN:NBN:fi:aalto-201609234408
dc.identifier.doi 10.1016/S0022-328X(99)00711-1
dc.type.version acceptedVersion


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