Hydrogenation of 4-deoxy-beta-L-threo-hex-4-enopyranosyluronic acid sodium salt attached to xylodiose or xylotriose

Selkälä, Sami A.; Alakurtti, Sami; Koskinen, Ari M.P.

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Hydrogenation of 4-deoxy-beta-L-threo-hex-4-enopyranosyluronic acid sodium salt attached to xylodiose or xylotriose

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Title:	Hydrogenation of 4-deoxy-beta-L-threo-hex-4-enopyranosyluronic acid sodium salt attached to xylodiose or xylotriose
Author(s):	Selkälä, Sami A. ; Alakurtti, Sami ; Koskinen, Ari M.P.
Date:	2001
Language:	en
Pages:	3215-3217
Department:	Department of Chemistry
Series:	Tetrahedron Letters, Volume 42
ISSN:	1873-3581
DOI-number:	10.1016/S0040-4039(01)00398-7
Keywords:	heterogenous catalysis, homogenous catalysis, hydrogenation, unsaturated acid
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Citation: Selkälä , S A , Alakurtti , S & Koskinen , A M P 2001 , ' Hydrogenation of 4-deoxy-beta-L-threo-hex-4-enopyranosyluronic acid sodium salt attached to xylodiose or xylotriose ' Tetrahedron Letters , vol 42 , pp. 3215-3217 . DOI: 10.1016/S0040-4039(01)00398-7
Abstract: A sodium salt of 4-deoxy-b-L-threo -hex-4-enopyranosyluronic acid 1 attached to xylodiose or xylotriose is hydro-genated for the first time. Moreover, the double bond of 4-deoxy-b-L-threo -hex-4-enopyranosyluronic acid sodium salt 1 can be reduced by hydrogenation in water without removing the allylic hydroxyl group. Highly active homogeneous catalysts and heterogeneous catalysts were tested and only palladium or platinum on charcoal catalysts were found to be active in this case.

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