Highly Chemoselective Copper-Catalyzed Conjugate Reduction of Stereochemically Labile alpha,beta-Unsaturated Amino Ketones

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Title:	Highly Chemoselective Copper-Catalyzed Conjugate Reduction of Stereochemically Labile alpha,beta-Unsaturated Amino Ketones
Author(s):	Pelss, Andrejs ; Kumpulainen, Esa T.T. ; Koskinen, Ari M.P.
Date:	2009
Language:	en
Pages:	7598-7601
Department:	Department of Chemistry
Series:	JOURNAL OF ORGANIC CHEMISTRY, Volume 74, issue 19
ISSN:	0022-3263 1520-6904
DOI-number:	10.1021/jo9017588
Subject:	116 Chemical sciences
Keywords:	116 Chemical sciences
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Citation: Pelss , A , Kumpulainen , E T T & Koskinen , A M P 2009 , ' Highly Chemoselective Copper-Catalyzed Conjugate Reduction of Stereochemically Labile alpha,beta-Unsaturated Amino Ketones ' JOURNAL OF ORGANIC CHEMISTRY , vol 74 , no. 19 , pp. 7598-7601 . DOI: 10.1021/jo9017588
Abstract: Highly chemoselective conjugate reduction of chiral R,β-unsaturated amino ketones has been developed by using triisopropyl phosphite ligated copper hydride complex. The highlights of the method are wide substrate compatibility and exceptional chemoselectivity.

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