Enantioselective synthesis of a hindered furyl substituted allyl alcohol intermediate: a case study in asymmetric synthesis

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dc.contributor Aalto-yliopisto fi
dc.contributor Aalto University en
dc.contributor.author Koskinen, Ari M.P.
dc.contributor.author Pihko, Ainoliisa J.
dc.contributor.author Lundell, Katri
dc.contributor.author Kanerva, Liisa
dc.date.accessioned 2016-09-23T08:17:16Z
dc.date.issued 2004
dc.identifier.citation Koskinen , A M P , Pihko , A J , Lundell , K & Kanerva , L 2004 , ' Enantioselective synthesis of a hindered furyl substituted allyl alcohol intermediate: a case study in asymmetric synthesis ' TETRAHEDRON-ASYMMETRY , no. 15 , pp. 1637-1643 . DOI: /10.1016/j.tetasy.2004.04.004 en
dc.identifier.issn 0957-4166
dc.identifier.other PURE UUID: 945457e5-3b6b-455b-b726-6468b8db1c02
dc.identifier.other PURE ITEMURL: https://research.aalto.fi/en/publications/enantioselective-synthesis-of-a-hindered-furyl-substituted-allyl-alcohol-intermediate-a-case-study-in-asymmetric-synthesis(945457e5-3b6b-455b-b726-6468b8db1c02).html
dc.identifier.other PURE FILEURL: https://research.aalto.fi/files/7157238/1637.pdf
dc.identifier.uri https://aaltodoc.aalto.fi/handle/123456789/22330
dc.description.abstract In the course of the synthesis of the DEFG ring system of cneorin C 1, we were faced with the task of preparing the furyl substituted allyl alcohol 5 enantioselectively. Several different methods starting from enantioselective zinc-mediated alkylations were attempted, but none of them proved entirely satisfactory. The solution turned out to be enzymatic kinetic resolution through a highly enantioselective (E > 300) acylation in the presence of Candida antarctica lipase A. en
dc.format.extent 1637-1643
dc.format.mimetype application/pdf
dc.language.iso en en
dc.relation.ispartofseries TETRAHEDRON-ASYMMETRY en
dc.relation.ispartofseries issue 15 en
dc.rights openAccess en
dc.subject.other 116 Chemical sciences en
dc.title Enantioselective synthesis of a hindered furyl substituted allyl alcohol intermediate: a case study in asymmetric synthesis en
dc.type A1 Alkuperäisartikkeli tieteellisessä aikakauslehdessä fi
dc.description.version Peer reviewed en
dc.contributor.department Department of Chemistry en
dc.subject.keyword 116 Chemical sciences
dc.identifier.urn URN:NBN:fi:aalto-201609234334
dc.identifier.doi /10.1016/j.tetasy.2004.04.004
dc.type.version acceptedVersion


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