Hajos-Parrish ketone: approaches toward C-ring prcursors of 7-deoxytaxol

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dc.contributor Aalto-yliopisto fi
dc.contributor Aalto University en
dc.contributor.author Lajunen, M.
dc.contributor.author Koskinen, A.
dc.date.accessioned 2016-09-23T08:16:42Z
dc.date.issued 2000
dc.identifier.citation Lajunen , M & Koskinen , A 2000 , ' Hajos-Parrish ketone: approaches toward C-ring prcursors of 7-deoxytaxol ' Journal Chem. Soc., Perkin Trans. , no. 1 , pp. 1439-1443 . DOI: 10.1039/a909471g en
dc.identifier.other PURE UUID: 8896995d-4bef-429a-83d7-6388a25cc00d
dc.identifier.other PURE ITEMURL: https://research.aalto.fi/en/publications/hajosparrish-ketone-approaches-toward-cring-prcursors-of-7deoxytaxol(8896995d-4bef-429a-83d7-6388a25cc00d).html
dc.identifier.other PURE FILEURL: https://research.aalto.fi/files/7159156/ms076.PDF
dc.identifier.uri https://aaltodoc.aalto.fi/handle/123456789/22321
dc.description.abstract Two routes were evaluated for the preparation of multiply functionalized cyclohexane derivatives in a stereocontrolled fashion from readily available Hajos–Parrish ketone 1. Reduction (catalytic or dissolving metal) led to the cis-isomer 8, in stark contrast to previous literature. Finally, modification of earlier steroid chemistry allowed the synthesis of the trans-isomer 14. The latter is a useful intermediate for the synthesis of 7-deoxytaxol derivatives. en
dc.format.extent 1439-1443
dc.format.mimetype application/pdf
dc.language.iso en en
dc.relation.ispartofseries Journal Chem. Soc., Perkin Trans. en
dc.relation.ispartofseries issue 1 en
dc.rights openAccess en
dc.title Hajos-Parrish ketone: approaches toward C-ring prcursors of 7-deoxytaxol en
dc.type A1 Alkuperäisartikkeli tieteellisessä aikakauslehdessä fi
dc.description.version Peer reviewed en
dc.contributor.department Department of Chemistry en
dc.subject.keyword synthesis
dc.subject.keyword taxol
dc.identifier.urn URN:NBN:fi:aalto-201609234325
dc.identifier.doi 10.1039/a909471g
dc.type.version acceptedVersion


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