Model Studies Towards Alternative Cross-Linking of Unsaturated Polyesters

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Journal Title
Journal ISSN
Volume Title
A1 Alkuperäisartikkeli tieteellisessä aikakauslehdessä
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Date
2005
Major/Subject
Mcode
Degree programme
Language
en
Pages
74-76
Series
Letters in Organic Chemistry, Volume 2
Abstract
Fumaric and maleic acid esters are functionalised with propargylamine. A subsequent Pd/Cu-catalysed oxidative homo-coupling of two alkyne moieties yields the corresponding dimers. Hence, a model of an unsaturated polyester chain is cross-linked in a welldefined, metal-mediated reaction in a very high yield.
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Keywords
alkyne coupling, catalytic, cross-linking, unsaturated polyester
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Citation
Straub , T , Brunner , M & Koskinen , A M P 2005 , ' Model Studies Towards Alternative Cross-Linking of Unsaturated Polyesters ' , Letters in Organic Chemistry , vol. 2 , pp. 74-76 . https://doi.org/10.2174/1570178053399868