Monoalcoholates of 1,3-diols as effective catalysts in the Tishchenko esterification of 1,3-dioxan-4-ols

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dc.contributor Aalto-yliopisto fi
dc.contributor Aalto University en
dc.contributor.author Törmäkangas, Olli P.
dc.contributor.author Koskinen, Ari M.P.
dc.date.accessioned 2016-09-23T07:31:53Z
dc.date.issued 2001
dc.identifier.citation Törmäkangas , O P & Koskinen , A M P 2001 , ' Monoalcoholates of 1,3-diols as effective catalysts in the Tishchenko esterification of 1,3-dioxan-4-ols ' Tetrahedron Letters , vol 42 , pp. 2743-2746 . DOI: 10.1016/S0040-4039(01)00277-5 en
dc.identifier.issn 1873-3581
dc.identifier.other PURE UUID: 0f70ef95-7c8a-44ee-b88a-c6fefde4203f
dc.identifier.other PURE ITEMURL: https://research.aalto.fi/en/publications/monoalcoholates-of-13diols-as-effective-catalysts-in-the-tishchenko-esterification-of-13dioxan4ols(0f70ef95-7c8a-44ee-b88a-c6fefde4203f).html
dc.identifier.other PURE FILEURL: https://research.aalto.fi/files/7159281/ms080.pdf
dc.identifier.uri https://aaltodoc.aalto.fi/handle/123456789/22264
dc.description.abstract Alkali metal monoalcoholates of 1,3-diols can be used as very effective catalysts in the Tishchenko reaction of 4-hydroxy-1,3-dioxanes to the corresponding monoesters of 1,3-diols. These catalysts are extremely efficient and fast compared to metal hydroxides commonly used. Thus, monoalcoholate catalysts give fast transesterification with the product ester. The loss in yield due to ester interchange can be minimized by using a suitable 1,3-diol moiety in the catalyst. en
dc.format.extent 2743-2746
dc.format.mimetype application/pdf
dc.language.iso en en
dc.relation.ispartofseries Tetrahedron Letters en
dc.relation.ispartofseries Volume 42 en
dc.rights openAccess en
dc.title Monoalcoholates of 1,3-diols as effective catalysts in the Tishchenko esterification of 1,3-dioxan-4-ols en
dc.type A1 Alkuperäisartikkeli tieteellisessä aikakauslehdessä fi
dc.description.version Peer reviewed en
dc.contributor.department Department of Chemistry en
dc.subject.keyword alcoholate
dc.subject.keyword dioxanol
dc.subject.keyword esterification
dc.subject.keyword hydride shift
dc.subject.keyword Tishchenko reaction
dc.identifier.urn URN:NBN:fi:aalto-201609234268
dc.identifier.doi 10.1016/S0040-4039(01)00277-5
dc.type.version acceptedVersion


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