Electrochemistry at electrified soft interfaces : novel approaches to old problems

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dc.contributor Aalto-yliopisto fi
dc.contributor Aalto University en
dc.contributor.author Liljeroth, Peter
dc.date.accessioned 2012-02-10T09:33:41Z
dc.date.available 2012-02-10T09:33:41Z
dc.date.issued 2002-09-28
dc.identifier.isbn 951-22-6119-7
dc.identifier.uri https://aaltodoc.aalto.fi/handle/123456789/2219
dc.description.abstract This thesis addresses some known difficulties in the field of liquid | liquid electrochemistry by presenting novel means of controlling mass transfer, monolayermodification of the interface, and probing interfacial reactivity. A novel rectangular channel flow electrochemical cell suitable for studying charge transfer at liquid | liquid interfaces is presented. The organic phase is immobilised using a gelling agent, while the aqueous phase flows past the interface. This creates an asymmetric diffusion regime, providing diagnostic criteria to determine, for example, the direction of the ion transfer. One of enduring problems concerning phospholipid adsorption at liquid | liquid interfaces has been the inability to determine and control the exact nature of the adsorbed monomolecular layer. This difficulty is addressed by a combination of the Langmuir-Blodgett technique and the use of an electrochemical cell as a substrate. It is shown that reproducible layers of known surface pressure can be deposited at the interface and that the deposition surface pressure has a great influence on the behaviour of the layer. The latter part of this thesis concerns the study of reactivity at liquid | liquid interfaces. To this end, the potential of ring-disk ultramicroelectrodes as probes for scanning electrochemical microscopy is investigated both theoretically and experimentally. In particular, the disk-generation/ring-collection mode of operation is considered. The interaction of two species with the substrate under investigation can be followed simultaneously from a single tip current-distance measurement to the substrate. This method is then applied to investigate the partitioning of iodine across a liquid-liquid interface. A facile method to determine the lipophilicity of potentially unstable charged products of electron transfer reactions is reported. This is achieved by local electrolysis at a Pt coated micropipette and subsequent transfer of the electrogenerated ions across a polarisable liquid | liquid interface supported at the tip of the micropipette. The formal potential of ion transfer can then be used to give a measure of its relative lipophilicity. en
dc.format.extent 53
dc.format.mimetype application/pdf
dc.language.iso en en
dc.publisher Helsinki University of Technology en
dc.publisher Teknillinen korkeakoulu fi
dc.relation.haspart Peter Liljeroth, Cristoffer Johans, Kyösti Kontturi, José A. Manzanares. Channel Flow at an Immobilised Liquid | Liquid Interface. Journal of Electroanalytical Chemistry. Vol. 483 (2000), pp. 37-46. [article1.pdf] © 2000 Elsevier Science. By permission.
dc.relation.haspart Peter Liljeroth, Annika Mälkiä, Vincent J. Cunnane, Anna-Kaisa Kontturi, Kyösti Kontturi. Langmuir-Blodgett Monolayers at Liquid-Liquid Interface. Langmuir. Vol. 16 (2000), pp. 6667-6673. [article2.pdf] © 2000 American Chemical Society. By permission.
dc.relation.haspart Peter Liljeroth, Christoffer Johans, Christopher J. Slevin, Bernadette M. Quinn, Kyösti Kontturi. Micro Ring-Disk Electrode Probes for Scanning Electrochemical Microscopy. Electrochemistry Communications. Vol. 4 (2002), pp. 67-71. [article3.pdf] © 2002 Elsevier Science. By permission.
dc.relation.haspart Peter Liljeroth, Christoffer Johans, Christopher J. Slevin, Bernadette M. Quinn, Kyösti Kontturi. Disk-Generation / Ring-Collection Scanning Electrochemical Microscopy: Theory and Application. Analytical Chemistry. Vol. 74 (2002), pp. 1972-1978. [article4.pdf] © 2002 American Chemical Society. By permission.
dc.relation.haspart Peter Liljeroth, Bernadette M. Quinn, Kyösti Kontturi. Lipophilicity of Ions Electrogenerated at a Pt Coated Micropipette Supported Liquid-Liquid Interface. Electrochemistry Communications. Vol. 4 (2002), pp. 255-259. [article5.pdf] © 2002 Elsevier Science. By permission.
dc.subject.other Chemistry en
dc.title Electrochemistry at electrified soft interfaces : novel approaches to old problems en
dc.type G5 Artikkeliväitöskirja fi
dc.description.version reviewed en
dc.contributor.department Department of Chemical Technology en
dc.contributor.department Kemian tekniikan osasto fi
dc.subject.keyword electrochemistry en
dc.subject.keyword liquid-liquid interface en
dc.subject.keyword Langmuir-Blodgett technique en
dc.subject.keyword channel flow cell en
dc.subject.keyword scanning electrochemical microscopy en
dc.identifier.urn urn:nbn:fi:tkk-001890
dc.type.dcmitype text en
dc.type.ontasot Väitöskirja (artikkeli) fi
dc.type.ontasot Doctoral dissertation (article-based) en
dc.contributor.lab Laboratory of Physical Chemistry and Electrochemistry en
dc.contributor.lab Fysikaalisen kemian ja sähkökemian laboratorio fi


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