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Densities of Molten and Solid Alloys of (Fe, Cu, Ni, Co)-S at Elevated Temperatures - Literature Review and Analysis

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dc.contributor Aalto-yliopisto fi
dc.contributor Aalto University en
dc.contributor.author Tesfaye, Fiseha
dc.contributor.author Taskinen, Pekka
dc.date.accessioned 2014-10-13T05:54:34Z
dc.date.available 2014-10-13T05:54:34Z
dc.date.issued 2010
dc.identifier.citation Tesfaye, Fiseha & Taskinen, Pekka. 2010. Densities of Molten and Solid Alloys of (Fe, Cu, Ni, Co)-S at Elevated Temperatures - Literature Review and Analysis. Teknillisen korkeakoulun materiaalitekniikan julkaisuja. TKK-MT-215. ISSN 1455-2329 (printed). ISBN 978-952-60-3272-6 (printed). en
dc.identifier.isbn 978-952-60-3272-6 (printed)
dc.identifier.issn 1455-2329 (printed)
dc.identifier.uri https://aaltodoc.aalto.fi/handle/123456789/14194
dc.description.abstract Densities of solid and liquid Fe, Cu, Ni and Co, and their alloys both at the presence and absence of sulfur have been reviewed. Volumetric thermal expansions were used to estimate the densities at different temperatures. Densities of the alloys generally decrease with increasing temperature. For the pure metals the reduction in density as temperature rises from 25 oC to their respective melting point can be estimated to be about 7.05 ± 0.4 % just before melting and about 11.63 ± 0.92 on complete melting. According to the literature data and the analyzed results, at ambient pressure condition, density of the stoichiometric FeS changes from 4.615 g/cm3 at 25 oC to 3.8 g/cm3 at 1200 oC (17.7 %), density of the stoichiometric Cu2S changes from 5.65 g/cm3 at 25 oC to 5.18 g/cm3 at 1200 oC (8.3 %), density of the stoichiometric NiS changes from 5.5 g/cm3 at 25 oC to 5.025 g/cm3 at 1027 oC (8.5 ± 1.8 %) and density of the stoichiometric CoS changes from 5.45 g/cm3 at 25 oC to 4.88 g/cm3 at 1100 oC (10.45 %). A study on the Fe-S melts at 4GPa suggests that in sulfur-poor compositions, where solubility of sulfur is less likely to be affected by pressure, the density of the sulfides at isothermal conditions decreases in a similar fashion as under 1 bar, i.e., density decreases non-linearly with increasing composition of sulfur. en
dc.format.extent 31
dc.format.mimetype application/pdf en
dc.language.iso en en
dc.publisher Aalto University Publications in Materials Science and Engineering en
dc.publisher Aalto-yliopiston materiaalitekniikan julkaisuja fi
dc.relation.ispartofseries Teknillisen korkeakoulun materiaalitekniikan julkaisuja en
dc.relation.ispartofseries TKK-MT-215
dc.subject.other Chemistry en
dc.subject.other Energy en
dc.subject.other Materials science en
dc.subject.other Metallurgy en
dc.title Densities of Molten and Solid Alloys of (Fe, Cu, Ni, Co)-S at Elevated Temperatures - Literature Review and Analysis en
dc.type D4 Julkaistu kehittämis- tai tutkimusraportti tai -selvitys fi
dc.description.version Peer reviewed en
dc.rights.holder Fiseha Tesfaye
dc.contributor.school Kemian tekniikan korkeakoulu fi
dc.contributor.school School of Chemical Technology en
dc.contributor.department Materiaalitekniikan laitos fi
dc.contributor.department Department of Materials Science and Engineering en
dc.subject.keyword Density en
dc.subject.keyword Thermal expansion coefficient en
dc.subject.keyword Molar volume en
dc.subject.keyword Sulfide en
dc.subject.keyword Fe en
dc.subject.keyword Co en
dc.subject.keyword Ni en
dc.subject.keyword Cu en
dc.identifier.urn URN:NBN:fi:aalto-201410132805
dc.type.dcmitype text en
dc.contributor.lab Metallurgical Thermodynamics and Modelling Research Group en
dc.contributor.lab Metallurgisten prosessien termodynamiikan ja mallinnuksen tutkimusryhmä fi
dc.type.version Final published version en


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