Title: | Measurements and modeling of physical properties for oil and biomaterial refining |
Author(s): | Zaitseva, Anna |
Date: | 2014 |
Language: | en |
Pages: | 84 + app. 145 |
Department: | Biotekniikan ja kemian tekniikan laitos Department of Biotechnology and Chemical Technology |
ISBN: | 978-952-60-5751-4 (electronic) 978-952-60-5750-7 (printed) |
Series: | Aalto University publication series DOCTORAL DISSERTATIONS, 94/2014 |
ISSN: | 1799-4942 (electronic) 1799-4934 (printed) 1799-4934 (ISSN-L) |
Supervising professor(s): | Alopaeus, Ville, Professor, Aalto University, Department of Biotechnology and Chemical Technology, Finland |
Thesis advisor(s): | Uusi-Kyyny, Petri, D.Sc (Tech), Aalto University, Department of Biotechnology and Chemical Technology, Finland; Pokki, Juha-Pekka, D.Sc (Tech), Aalto University, Department of Biotechnology and Chemical Technology, Finland |
Subject: | Chemistry |
Keywords: | vapor-liquid equilibrium, excess enthalpy, furfural, COSMO-RS, UNIFAC, headspace gas chromatography, recirculation still apparatus, static total pressure apparatus |
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Abstract:The aim of this thesis was to investigate a set of binary systems for developing necessary thermodynamic models for oil and biofuel industries. Extensive experimental work was performed for supplying the necessary vapor – liquid equilibria (VLE) and excess enthalpy data for the selected systems.
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Parts:[Publication 1]: Zaitseva, A. and Alopaeus, V. Improving group contribution methods by distance weighting | Amélioration de la méthode de contribution du groupe en pondérant la distance du groupe. Oil and Gas Science and Technology (2013), vol. 68, no. 2, pp. 235-247.[Publication 2]: Zaitseva, A.; Laavi H.; Pokki J.-P.; Uusi-Kyyny P. and Alopaeus V. Isothermal Vapor-Liquid Equilibrium and Excess Molar Enthalpies of the binary mixtures furfural + methyl isobutyl ketone, + 2-butanol and + 2-methyl-2-butanol. Fluid Phase Equilibria (2014), 372, 85–99.[Publication 3]: Laavi, H.; Zaitseva, A.; Pokki, J.-P.; Uusi-Kyyny, P.; Kim, Y.; Alopaeus, V. Vapor-liquid equilibrium, excess molar enthalpies, and excess molar volumes of binary mixtures containing methyl isobutyl ketone (MIBK) and 2-butanol, tert-pentanol, or 2-ethyl-1-hexanol. Journal of Chemical and Engineering Data (2012), vol. 57, n. 11, pp. 3092-3101.[Publication 4]: Zaytseva, A.; Uusi-Kyyny, P.; Pokki, J.-P.; Pakkanen, M.; Aittamaa, J. Vapor-Liquid Equilibrium for the trans-2-Butene + Methanol, + Ethanol, + 2-Propanol, + 2-Butanol, and + 2-Methyl-2-propanol Systems at 332 K. Journal of Chemical and Engineering Data (2004), 49(5), 1168-1174.[Publication 5]: Dell'Era, C.; Zaytseva, A.; Uusi-Kyyny, P.; Pokki, J.-P.; Pakkanen, M.; Aittamaa, J. Vapour-liquid equilibrium for the systems butane + methanol, +2-propanol, +1-butanol, +2-butanol, +2-methyl-2-propanol at 364.5 K. Fluid Phase Equilibria (2007), 254(1-2), 49-59.[Publication 6]: Pasanen, M.; Zaytseva, A.; Uusi-Kyyny, P.; Pokki, J.–P.; Pakkanen, M.; Aittamaa, J. Vapor Liquid Equilibrium for Six Binary Systems of C4-Hydrocarbons + 2-Propanone. Journal of Chemical & Engineering Data (2006), 51(2), 554-561.[Publication 7]: Ouni, T.; Zaytseva, A.; Uusi-Kyyny, P.; Pokki, J.-P.; Aittamaa, J. Vapour-liquid equilibrium for the 2-methylpropane + methanol, +ethanol, +2-propanol, +2-butanol and +2-methyl-2-propanol systems at 313.15K. Fluid Phase Equilibria (2005), 232(1-2), 90-99.[Publication 8]: Sapei, E.; Zaytseva, A; Uusi-Kyyny, P; Younghun, K; Keskinen, K. I.; Aittamaa, J. Vapor-Liquid Equilibrium for Binary System of 1-Propanethiol, Thiophene, and Diethyl Sulfide with Toluene at 90.03 kPa. Journal of Chemical & Engineering Data (2006), 51(4), 1372-1376.[Publication 9]: Sapei, E.; Zaytseva, A.; Uusi-Kyyny, P.; Keskinen, K. I.; Aittamaa, J. Vapor-Liquid Equilibrium for Binary System of Diethyl Sulfide + n-Hexane at (338.15 and 323.15) K and Diethyl Sulfide + 1-Hexene at (333.15 and 323.15) K. Journal of Chemical & Engineering Data (2007), 52(2), 571-576.[Publication 10]: Sapei, E.; Zaytseva, A.; Uusi-Kyyny, P.; Keskinen, K. I.; Aittamaa, J. Vapor-Liquid Equilibrium for Binary System of Diethyl Sulfide + n-Heptane and Diethyl Sulfide + 2,2,4-Trimethylpentane at (363.15 and 353.15) K. Journal of Chemical & Engineering Data (2007), 52(1), 192-198.[Publication 11]: Sapei, E.; Zaytseva, A.; Uusi-Kyyny, P.; Keskinen, K. I.; Aittamaa, J. Vapor-liquid equilibrium for binary system of diethyl sulfide + cyclohexane at 353.15 and 343.15K and diethyl sulfide + 2-ethoxy-2-methylpropane at 343.15 and 333.15K. Fluid Phase Equilibria (2007), 252(1-2), 130-136.[Publication 12]: Sapei, E.; Zaytseva, A.; Uusi-Kyyny, P.; Keskinen, K. I.; Aittamaa, J. Vapor-Liquid Equilibrium for Binary System of Thiophene + n-Hexane at (338.15 and 323.15) K and Thiophene + 1-Hexene at (333.15 and 323.15) K. Journal of Chemical & Engineering Data (2006), 51(6), 2203-2208.[Publication 13]: Sapei, E.; Zaytseva, A.; Uusi-Kyyny, P.; Keskinen, K. I.; Aittamaa, J. Vapor-liquid equilibrium for binary system of thiophene+2,2,4-trimethylpentane at 343.15 and 353.15K and thiophene+2-ethoxy-2-methylpropane at 333.15 and 343.15K. Fluid Phase Equilibria (2007), 261(1-2), 115-121. |
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