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Benzenedisulfonic Acid as an ALD/MLD Building Block for Crystalline Metal-Organic Thin Films**

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dc.contributor Aalto-yliopisto fi
dc.contributor Aalto University en
dc.contributor.author Heiska, Juho
dc.contributor.author Sorsa, Olli
dc.contributor.author Kallio, Tanja
dc.contributor.author Karppinen, Maarit
dc.date.accessioned 2021-07-01T13:07:55Z
dc.date.available 2021-07-01T13:07:55Z
dc.date.issued 2021-06-16
dc.identifier.citation Heiska , J , Sorsa , O , Kallio , T & Karppinen , M 2021 , ' Benzenedisulfonic Acid as an ALD/MLD Building Block for Crystalline Metal-Organic Thin Films** ' , Chemistry - A European Journal , vol. 27 , no. 34 , pp. 8799-8803 . https://doi.org/10.1002/chem.202100538 en
dc.identifier.issn 0947-6539
dc.identifier.issn 1521-3765
dc.identifier.other PURE UUID: 96a47dc6-b135-4363-9f0e-92e877811f63
dc.identifier.other PURE ITEMURL: https://research.aalto.fi/en/publications/96a47dc6-b135-4363-9f0e-92e877811f63
dc.identifier.other PURE LINK: http://www.scopus.com/inward/record.url?scp=85105333389&partnerID=8YFLogxK
dc.identifier.other PURE FILEURL: https://research.aalto.fi/files/65289775/CHEM_Heiska_et_al_Benzenedisulfonic_Acid_2021_Chemistry_A_European_Journal.pdf
dc.identifier.uri https://aaltodoc.aalto.fi/handle/123456789/108621
dc.description Funding Information: The authors would like to thank the Academy of Finland (Profi 3 and 5 projects) and the European Union's Horizon 2020 research and innovation program under grant agreement CREATE No. 721065 for funding this work. This study made use of RawMatTERS Finland Infrastructure (Aalto – RAMI). Publisher Copyright: © 2021 The Authors. Chemistry - A European Journal published by Wiley-VCH GmbH Copyright: Copyright 2021 Elsevier B.V., All rights reserved.
dc.description.abstract ** ALD=atomic layer deposition; MLD=molecular layer deposition. Two new atomic/molecular layer deposition processes for depositing crystalline metal-organic thin films, built from 1,4-benzenedisulfonate (BDS) as the organic linker and Cu or Li as the metal node, are reported. The processes yield in-situ crystalline but hydrated Cu-BDS and Li-BDS films; in the former case, the crystal structure is of a previously known metal-organic-framework-like structure, while in the latter case not known from previous studies. Both hydrated materials can be readily dried to obtain the crystalline unhydrated phases. The stability and the ionic conductivity of the unhydrated Li-BDS films were characterized to assess their applicability as a thin film solid polymer Li-ion conductor. en
dc.format.extent 5
dc.format.extent 8799-8803
dc.format.mimetype application/pdf
dc.language.iso en en
dc.publisher WILEY-V C H VERLAG GMBH
dc.relation.ispartofseries Chemistry - A European Journal en
dc.relation.ispartofseries Volume 27, issue 34 en
dc.rights openAccess en
dc.title Benzenedisulfonic Acid as an ALD/MLD Building Block for Crystalline Metal-Organic Thin Films** en
dc.type A1 Alkuperäisartikkeli tieteellisessä aikakauslehdessä fi
dc.description.version Peer reviewed en
dc.contributor.department Department of Chemistry and Materials Science
dc.contributor.department Electrochemical Energy Conversion
dc.subject.keyword atomic layer deposition
dc.subject.keyword metal-organic frameworks
dc.subject.keyword molecular layer deposition
dc.subject.keyword solid electrolyte
dc.subject.keyword sulfonate
dc.identifier.urn URN:NBN:fi:aalto-202107017875
dc.identifier.doi 10.1002/chem.202100538
dc.type.version publishedVersion

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