Browsing by Author "Huang, Ying-Sheng"

Now showing 1 - 2 of 2

Single-Layer ReS2 : Two-Dimensional Semiconductor with Tunable In-Plane Anisotropy
(2015-11) Lin, Yung-Chang; Komsa, Hannu-Pekka; Yeh, Chao-Hui; Björkman, Torbjörn; Liang, Zheng-Yong; Ho, Ching-Hwa; Huang, Ying-Sheng; Chiu, Po-Wen; Krasheninnikov, Arkady V.; Suenaga, Kazu
A1 Alkuperäisartikkeli tieteellisessä aikakauslehdessä
Rhenium disulfide (ReS2) and diselenide (ReSe2), the group 7 transition metal dichalcogenides (TMDs), are known to have a layered atomic structure showing an in-plane motif of diamond-shaped-chains (DS-chains) arranged in parallel. Using a combination of transmission electron microscopy and transport measurements, we demonstrate here the direct correlation of electron transport anisotropy in single-layered ReS2 with the atomic orientation of the DS-chains, as also supported by our density functional theory calculations. We further show that the direction of conducting channels in ReS2 and ReSe2 can be controlled by electron beam irradiation at elevated temperatures and follows the strain induced to the sample. Furthermore, high chalcogen deficiency can induce a structural transformation to a nonstoichiometric phase, which is again strongly direction-dependent. This tunable in-plane transport behavior opens up great avenues for creating nanoelectronic circuits in 2D materials.
Three-fold rotational defects in two-dimensional transition metal dichalcogenides
(2015-04) Lin, Yung-Chang; Björkman, Torbjörn; Komsa, Hannu-Pekka; Teng, Po-Yuan; Yeh, Chao-Hui; Huang, Fei-Sheng; Lin, Kuan-Hung; Jadczak, Joanna; Huang, Ying-Sheng; Chiu, Po-Wen; Krasheninnikov, Arkady V.; Suenaga, Kazu
A1 Alkuperäisartikkeli tieteellisessä aikakauslehdessä
As defects frequently govern the properties of crystalline solids, the precise microscopic knowledge of defect atomic structure is of fundamental importance. We report a new class of point defects in single-layer transition metal dichalcogenides that can be created through 60 degrees rotations of metal-chalcogen bonds in the trigonal prismatic lattice, with the simplest among them being a three-fold symmetric trefoil-like defect. The defects, which are inherently related to the crystal symmetry of transition metal dichalcogenides, can expand through sequential bond rotations, as evident from in situ scanning transmission electron microscopy experiments, and eventually form larger linear defects consisting of aligned 8-5-5-8 membered rings. First-principles calculations provide insights into the evolution of rotational defects and show that they give rise to p-type doping and local magnetic moments, but weakly affect mechanical characteristics of transition metal dichalcogenides. Thus, controllable introduction of rotational defects can be used to engineer the properties of these materials.